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PGM ore is mined underground and less usually in
open-cast pits. It is blasted out of the ground before being crushed
and milled into smaller rock particles which are mixed with water
and reagents and pumped through with air to form a "froth
flotation".
PGM-rich particles adhere to the bubbles created by this process. They are
then removed at the surface and the remaining material is put through the
process a second time.
When dried, the flotation concentrate is smelted
at temperatures that may be over 1500 °C and a mixture of the
metals is separated from unwanted minerals such as iron and sulphur
by air being blown through.
Nickel, copper and cobalt are separated and refined
using electrolytic techniques leaving rich residues which require
the separation and purification of the remaining PGMs, gold and
silver. This part of the process is an intricate combination of
solvent extraction, distillation and ion-exchange techniques.
Finally, the soluble metals, which dissolve in hydrochloric
acid and chlorine gas, are obtained: first gold and then palladium
and platinum. The insoluble PGMs (rhodium, iridium, ruthenium and
osmium) are the last to be extracted.
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